The oxidation state in low-valent beryllium and magnesium compounds-Reference-Cited by-同舟云学术

The oxidation state in low-valent beryllium and magnesium compounds

Published:2022 Issue:22 Volume:13 Page:6583-6591
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gimferrer Martí¹^ORCID,Danés Sergi¹²,Vos Eva³,Yildiz Cem B.⁴^ORCID,Corral Inés³^ORCID,Jana Anukul⁵^ORCID,Salvador Pedro¹^ORCID,Andrada Diego M.²^ORCID

Affiliation:

1. Institut de Química Computacional i Catàlisi, Departament de Química, Universitat de Girona, c/M. Aurelia Capmany 69, 17003, Girona, Spain

2. General and Inorganic Chemistry Department, University of Saarland, Campus C4.1, 66123 Saarbruecken, Germany

3. Departamento de Química, Universidad Autónoma de Madrid, c/Francisco Tomás y Valiente 7, 28049 Cantoblanco Madrid, Spain

4. Department of Medicinal and Aromatic Plants, Aksaray University, Hacilar harmani 2, 68100 Aksaray, Turkey

5. Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad-500046, Telangana, India

Abstract

This article examines the electronic structure of group 2 (E = Be and Mg) ligand stabilized compounds. We elaborate on the donor–acceptor interaction L(0) ⇆ E(0) ⇆ L(0) and diradical L(−1) → E(+2) ← L(−1) pictures to assess the oxidation state of the metal.

Funder

Science and Engineering Research Board

Department of Atomic Energy, Government of India

H2020 European Research Council

Ministerio de Ciencia, Innovación y Universidades

Department d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01401G