Kinetic and mechanistic insights into Ni-AlKIT-6 catalyzed ethylene oligomerization-Reference-Cited by-同舟云学术

Kinetic and mechanistic insights into Ni-AlKIT-6 catalyzed ethylene oligomerization

Published:2022 Issue:1 Volume:7 Page:133-141
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Beucher Remi¹,Hulea Vasile¹^ORCID,Cammarano Claudia¹^ORCID

Affiliation:

1. Institut Charles Gerhardt Montpellier, UMR 5253, ICGM, CNRS, Univ Montpellier, ENSCM, Matériaux Avancés pour la Catalyse et la Santé, 34296 Montpellier, France

Abstract

An experimental study of the ethylene dimerization and isomerization performed on a mesoporous 2 wt% Ni-AIKIT-6 showed that the kinetically determining step is the insertion of ethylene in the metal–alkyl bond at the nickel site neighborhood.

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D1RE00258A

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