Unusually strong heteroatomic bonding in the complex polyanion of intermetallic Ba6Pt22Al53-Reference-Cited by-同舟云学术

Unusually strong heteroatomic bonding in the complex polyanion of intermetallic Ba6Pt22Al53

Published:2019 Issue:37 Volume:48 Page:14103-14114
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Stegemann Frank¹²³⁴,Touzani Rachid Stefan⁵⁶⁷⁴,Janka Oliver¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Westfälische Wilhelms-Universität Münster

3. 48149 Münster

4. Germany

5. Institut für Werkstoff- und Fügetechnik (IWF)

6. Otto-von-Guericke-Universität Magdeburg

7. 39104 Magdeburg

Abstract

Ba₆Pt₂₂Al₅₃exhibits a complex polyanion with an extremely short Pt–Al bond of 239 pm. DFT calculations show that this bond is a strong covalent interaction.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02653C

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