A novel high-yield route to organic derivatives of group 2 metals; X-ray structure of [{Ba(OTf)2}4(py)14]·py (OTf = OSO2CF3) and NMR spectral characterisation of [Ba(NR2)(µ-NR2)2Na(thf)2](R = SiMe3)-Reference-Cited by-同舟云学术

A novel high-yield route to organic derivatives of group 2 metals; X-ray structure of [{Ba(OTf)2}4(py)14]·py (OTf = OSO2CF3) and NMR spectral characterisation of [Ba(NR2)(µ-NR2)2Na(thf)2](R = SiMe3)

Published:1994 Issue:21 Volume: Page:2435-2436
ISSN:0022-4936
Container-title:J. Chem. Soc., Chem. Commun.
language:en
Short-container-title:J. Chem. Soc., Chem. Commun.

Author:

Frankland Andrew D.,Hitchcock Peter B.,Lappert Michael F.,Lawless Gerard A.

Publisher

Royal Society of Chemistry (RSC)

Subject

Molecular Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940002435

Reference11 articles.

1. The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)

2. Syntheses and structures of a series of very low coordinate barium compounds: Ba[N(SiMe3)2]2(THF)2, {Ba[N(SiMe3)2)]2(THF)}2, and {Ba[N(SiMe3)2]2}2

3. Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2]

4. Ligand influences on structure and reactivity in organoalkaline earth chemistry

5. Monomeric strontium and barium β-diketonate adducts with polyethers; the X-ray crystal structures of [Sr(Ph2ACAC)2(tetraglyme)] and [Ba(THD)2(tetraglyme)]

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