Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1991/C3/C39910000724
Reference14 articles.
1. The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)
2. Metal vapour synthesis of bis{1,3-bis(trimethylsilyl)cyclopentadienyl}-calcium, -strontium, and -barium compounds; X-ray structures of [M{η-C5H3-1,3-(SiMe3)2}2(thf)](M = Ca, Sr; thf = tetrahydrofuran)
3. Preparation of activated calcium, strontium, and barium powders by reduction of alkaline earth di-iodides
4. New developments in the organometallic chemistry of calcium, strontium and barium
5. Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba6(O)(OBut)11(OCEt2CH2O)(thf)3](thf = tetrahydrofuran)
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