Sulfur dioxide insertion reactions into metal–alkoxide bonds: synthesis and crystal structure of catena-bis(methylsulfito)bis(methanol)calcium; a one-dimensional polymer based on eight-coordinate calcium ions
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940002695
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1. Solvent-Free Volatile Alkoxides of the Alkaline-Earth Elements
2. A very large calcium dialkoxide molecular aggregate having a CdI2 core geometry: Ca9(OCH2CH2OMe)18(HOCH2CH2OMe)2
3. The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)
4. The synthesis and characterization of the group IIA homoleptic aryloxides under mild conditions, [M(OAr′)2]2, and the adducts [M(OAr′)2(L)x]·L (M = Ca, Sr, Ba; Ar′= 2,4,6,-tri-t-butyl-phenol; L THF, x = 3; M = Ba; L = DME, x = 2; and L = HMPA, x = 3); and the X-ray structure of [Sr(OAr′)2(THF)3]· 0.5THF
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