The synthesis and characterization of the group IIA homoleptic aryloxides under mild conditions, [M(OAr′)2]2, and the adducts [M(OAr′)2(L)x]·L (M = Ca, Sr, Ba; Ar′= 2,4,6,-tri-t-butyl-phenol; L THF, x = 3; M = Ba; L = DME, x = 2; and L = HMPA, x = 3); and the X-ray structure of [Sr(OAr′)2(THF)3]· 0.5THF-Reference-Cited by-同舟云学术

The synthesis and characterization of the group IIA homoleptic aryloxides under mild conditions, [M(OAr′)2]2, and the adducts [M(OAr′)2(L)x]·L (M = Ca, Sr, Ba; Ar′= 2,4,6,-tri-t-butyl-phenol; L THF, x = 3; M = Ba; L = DME, x = 2; and L = HMPA, x = 3); and the X-ray structure of [Sr(OAr′)2(THF)3]· 0.5THF

Published:1992-01 Issue:16 Volume:11 Page:1995-2007
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Drake Simon R.,Otway David J.,Hursthouse Michael B.,Malik K.M.Abdul

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference40 articles.

1. The synthesis of metal organic compounds of calcium, strontium and barium by ammonia gas-saturated ethereal solvents

2. A low temperature synthesis of barium organometallics via mixed ammonia-ethereal solvents

3. Preparation of activated calcium, strontium, and barium powders by reduction of alkaline earth di-iodides

4. The synthesis and structure of the alkaline earth metal organic compounds [M(OAr)2(thf)n][M = Ca, n= 3 (1) or 0; M = Ba, n= 4] and [{Ca(NR2)(µNR2)(thf)}2], and the X-ray structure of (1)(Ar = C6H2But2-2,6-Me-4; R = SiMe3; thf - OC4H8)

5. Synthesis and spectroscopic properties of bis(trimethylsilyl)amides of the alkaline-earth metals magnesium, calcium, strontium, and barium

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