On the control of the site of methylation of the cyanide complex [Mo2(η5-C5H5)2(CO)(CN)(µ-SR)2]–by the substituents of the thiolate bridges (R = Me, Pri, CF3)-Reference-Cited by-同舟云学术

On the control of the site of methylation of the cyanide complex [Mo2(η5-C5H5)2(CO)(CN)(µ-SR)2]–by the substituents of the thiolate bridges (R = Me, Pri, CF3)

Published:1994 Issue:18 Volume: Page:2191-2192
ISSN:0022-4936
Container-title:J. Chem. Soc., Chem. Commun.
language:en
Short-container-title:J. Chem. Soc., Chem. Commun.

Author:

Abasq Marie-Laurence,Pétillon François Y.,Talarmin Jean

Publisher

Royal Society of Chemistry (RSC)

Subject

Molecular Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/1994/C3/C39940002191

Reference6 articles.

1. Electrochemistry of dinuclear, thiolate-bridged transition-metal compounds. 7. Electrochemical generation of isomers of [Mo2Cp2(CO)2(.mu.-SMe)2] and their reactivity toward isocyanide ligands

2. Emergence of a CNH and cyano complex based organometallic chemistry

3. Synthesis and reactivity of dienyl–metal compounds. Part 30. Alkylation of thiolato bridges: a route to stable dialkyl sulphide bridged dinuclear molybdenum complexes. Crystal structure determination of [(η-C5H5)(CO)Mo(µ-SMe2)2Mo(PMe3)(η-C5H5)][BF4]2

4. Protonation sites in thiolato iron carbonylates: evidence for an arrested Fe(RS-H) oxidative addition

5. Mechanistic study of hydrogen activation by cationic dinuclear (.mu.-sulfido)molybdenum complexes

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2. Trifluoromethylation of 2D Transition Metal Dichalcogenides: A Mild Functionalization and Tunable p‐Type Doping Method;Angewandte Chemie;2024-04-23

3. Methylation sites in tris(μ-thiolato)dimolybdenum(III) complexes;Journal of Organometallic Chemistry;2006-02

4. Control of the reactivity of trans-[Mo2(cp)2(CO)(YZ)(μ -SR)2] (cp = η-C5H5; YZ = CO or CN−) by the sulfur substituents (R = Me, Pri, But, Ph or CF3). Crystal structure of trans-[Mo2(cp)2(CO)(CNMe)(μ- SCF3)2];Journal of the Chemical Society, Dalton Transactions;1997

5. Electrochemical deprotection of a substrate binding site in [Mo2(cp)2(µ-SMe)3(µ-Cl)](cp =η5-C5H5)via chloride-bridge opening. Kinetics of MeCN and ButNC binding at this site;J. Chem. Soc., Dalton Trans.;1996