Copper-catalyzed diastereoselective synthesis of β-boryl-α-quaternary carbon carboxylic esters
Author:
Affiliation:
1. College of Natural Resources and Environment
2. Northwest A&F University
3. Yangling 712100
4. P. R. China
5. College of Chemistry and Pharmacy
6. Xi'an Gaoxin No.1 High School
7. Xi'an 710075
Abstract
Cu(i)-Catalyzed diastereoselective carboboration of α-alkyl-substituted α,β-unsaturated carboxylic esters to produce β-boryl-α-quaternary carbon esters was developed.
Funder
Natural Science Foundation of Shaanxi Province
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB02469C
Reference67 articles.
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4. Contiguous stereogenic quaternary carbons: A daunting challenge in natural products synthesis
5. Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
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