Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres-Reference-Cited by-同舟云学术

Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon stereocentres

Published:2014 Issue:84 Volume:50 Page:12597-12611
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Minko Yury¹²³⁴,Marek Ilan¹²³⁴

Affiliation:

1. The Mallat Family Laboratory of Organic Chemistry

2. Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry

3. Technion – Israel Institute of Technology

4. Haifa 320008, Israel

Abstract

Formation of highly diastereo- and enantiomerically enriched quaternary stereocentres from stereodefined acyclic trisubstituted metal enolates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC04391J

Reference86 articles.

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2. Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

3. Creation of quaternary stereocenters in carbonyl allylation reactions

4. Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis , ed. J. Christoffers and A. Baro , Wiley-VCH , Weinheim , 2005

5. The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

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