A novel stibacarbaborane cluster with adjacent antimony atoms exhibiting unique pnictogen bond formation that dominates its crystal packing-Reference-Cited by-同舟云学术

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A novel stibacarbaborane cluster with adjacent antimony atoms exhibiting unique pnictogen bond formation that dominates its crystal packing

Published:2017 Issue:40 Volume:46 Page:13714-13719
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Holub Josef¹²³,Melichar Petr⁴⁵³,Růžičková Zdeňka⁶⁷⁸⁹³,Vrána Jan⁶⁷⁸⁹³,Wann Derek A.¹⁰¹¹¹²¹³^ORCID,Fanfrlík Jindřich⁴⁵³,Hnyk Drahomír¹²³^ORCID,Růžička Aleš⁶⁷⁸⁹³

Affiliation:

1. Institute of Inorganic Chemistry of the Czech Academy of Sciences

2. 250 68 Husinec-Řež

3. Czech Republic

4. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences

5. 166 10 Prague 6

6. Department of General and Inorganic Chemistry

7. Faculty of Chemical Technology

8. University of Pardubice

9. 53210 Pardubice

10. Department of Chemistry

11. University of York

12. York

13. UK

Abstract

The reaction ofarachno-4,6-C₂B₇H₁₃with SbCl₃yieldsnido-7,8,9,11-Sb₂C₂B₇H₉, which simultaneously has Sb–Sb, Sb–B and Sb–C bonds and a unique ability to form pnictogen bonds.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02845H

Reference30 articles.

1. W. N. Lipscomb , Boron Hydrides, Benjamin, New York, 1963

2. D. Hnyk and D. A.Wann, Challenges and Advances in Computational Chemistry and Physics, in Boron – the Fifth Element, ed. D. Hnyk and M. McKee, Springer, Heidelberg, New York, Dordrecht and London, 2015, ch. 2, vol. 20

3. Bonding with boron

4. Group V boranes. 4. Icosahedral stibaboranes and their cyclopentadienylcobalt(III) complexes

5. Monocarbon carboranes. IV. Polyhedral arsa- and stibacarbadodecaborane(11) derivatives and related 11-atom cage fragments

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1. A computational study to determine the role of σ-hole in Br/OH substituted nido-carborane and its binding capabilities;Journal of Molecular Graphics and Modelling;2024-03

2. The Telluraboranes closo‐TeB₅Cl₅ and closo‐TeB₁₁Cl₁₁ with Exceptionally Long Body Diagonals: Synthetic and Bonding Motifs for Innovative Octahedral and Icosahedral Geometries;Angewandte Chemie International Edition;2023-05-04

3. closo‐TeB₅Cl₅ und closo‐TeB₁₁Cl₁₁ – polyedrische Telluraborane mit ungewöhnlich langen Raumdiagonalen: Synthese und Bindungsstudien an innovativen oktaedrischen und ikosaedrischen Geometrien;Angewandte Chemie;2023-05-04

4. Two Shared Icosahedral Metallacarboranes through Iron: A Joint Experimental and Theoretical Refinement of Mössbauer Spectrum in [Fe(1,2-C₂B₉H₁₁)₂]Cs;ACS Omega;2023-04-07

5. The pnictogen bond forming ability of bonded bismuth atoms in molecular entities in the crystalline phase: a perspective;CrystEngComm;2023

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