Reversible addition of terminal alkenes to digermynes-Reference-Cited by-同舟云学术

Reversible addition of terminal alkenes to digermynes

Published:2018 Issue:5 Volume:54 Page:519-522
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sugahara Tomohiro¹²³⁴,Guo Jing-Dong¹²³⁴,Sasamori Takahiro⁵⁶⁷⁸⁹^ORCID,Nagase Shigeru¹⁰¹¹¹²¹³⁴,Tokitoh Norihiro¹²³⁴^ORCID

Affiliation:

1. Institute for Chemical Research

2. Kyoto University, Gokasho Uji

3. Kyoto 611-0011

4. Japan

5. Graduate School of Natural Sciences

6. Nagoya City University

7. Yamanohata 1

8. Mizuho-cho

9. Mizuho-ku

10. Fukui Institute for Fundamental Chemistry

11. Kyoto University

12. Sakyo-ku

13. Kyoto 606-8103

Abstract

Stable digermynes with sterically demanding Bbt (Bbt = 2,6-[CH(SiMe₃)₂]₂-4-[C(SiMe₃)₃]-C₆H₂) or Tbb (Tbb = 4-tBu-2,6-[CH(SiMe₃)₂]₂-C₆H₂) groups underwent reversible [2+2] cycloadditions with terminal alkenes to give the corresponding 1,2-digermacyclobutenes.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C7CC08555A

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