A new method for synthesizing terminal olefins from esters using the Corey–Chaykovsky reagent-Reference-Cited by-同舟云学术

A new method for synthesizing terminal olefins from esters using the Corey–Chaykovsky reagent

Published:2024 Issue:25 Volume:22 Page:5093-5096
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Shi Hucheng¹,Yue Guoren¹²^ORCID,Yan Penji²,Ji Xiangdong²,Wei Yangfei²,Song Hai²,Jia Xin¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China

2. Key Laboratory of Hexi Corridor Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Hexi University, Zhangye, Gansu 734000, PR China

Abstract

A new synthetic method for terminal olefins was developed through the reaction of the Corey–Chaykovsky reagent with readily available esters. A mechanism involving nucleophilic addition, elimination and rearrangement is supported by DFT calculations.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D4OB00620H

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