Copper-catalyzed TEMPO oxidative cleavage of 1,3-diketones and β-keto esters for the synthesis of 1,2-diketones and α-keto esters
Author:
Affiliation:
1. Key Laboratory of Organic Synthesis of Jiangsu Province
2. College of Chemistry and Chemical Engineering
3. Soochow University
4. Suzhou
5. China
Abstract
Copper-catalyzed, TEMPO oxidized cleavage of α-methylene of 1,3-diketones and β-keto esters to form 1,2-diketones and α-keto esters.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00241F
Reference52 articles.
1. Biocatalytic Strategies for the Asymmetric Synthesis of α-Hydroxy Ketones
2. Multicomponent Dipolar Cycloaddition Strategy: Combinatorial Synthesis of Novel Spiro-Tethered Pyrazolo[3,4-b]quinoline Hybrid Heterocycles
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