Understanding the directed ortho lithiation of (R)-Ph2P(NCO2Me)NHCH(Me)Ph. NMR spectroscopic and computational study of the structure of the N-lithiated species-Reference-Cited by-同舟云学术

Understanding the directed ortho lithiation of (R)-Ph2P(NCO2Me)NHCH(Me)Ph. NMR spectroscopic and computational study of the structure of the N-lithiated species

Published:2014 Issue:38 Volume:43 Page:14291-14301
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Casimiro M.¹²³,García-López J.¹²³,Iglesias M. J.¹²³,López-Ortiz F.¹²³

Affiliation:

1. Área de Química Orgánica

2. Universidad de Almería

3. 04120 Almería, Spain

Abstract

The multinuclear magnetic resonance and computational study of the structure of N-lithium (R)-Ph₂P(NCO₂Me)NHCH(Me)Ph revealed the origin of its diastereoselective ortho lithiation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00927D

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