Synthesis of P-stereogenic diarylphosphinic amides by directed lithiation: transformation into tertiary phosphine oxides via methanolysis, aryne chemistry and complexation behaviour toward zinc(ii)-Reference-Cited by-同舟云学术

Synthesis of P-stereogenic diarylphosphinic amides by directed lithiation: transformation into tertiary phosphine oxides via methanolysis, aryne chemistry and complexation behaviour toward zinc(ii)

Published:2016 Issue:5 Volume:45 Page:2008-2022
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

del Águila-Sánchez Miguel A.¹²³⁴,Navarro Yolanda¹²³⁴,García López Jesús¹²³⁴,Guedes Guilherme P.⁵⁶⁷⁸⁹,López Ortiz Fernando¹²³⁴

Affiliation:

1. Área de Química Orgánica

2. Universidad de Almería

3. 04120 Almería

4. Spain

5. Instituto de Ciências Exatas

6. Departamento de Química

7. Universidade Federal Rural do Rio de Janeiro

8. 23870-000 Seropédica

9. Brazil

Abstract

A general synthesis of P-stereogenic compoundsviaDoLi–electrophilic quenching of phosphinic amides and subsequent derivatizations is reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT02860D

Reference97 articles.

1. Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

2. Phosphorus Ligands in Asymmetric Catalysis, ed. A. Börner, Wiley-VCH, Weinheim, 2008

3. Transition Metal-Catalyzed Asymmetric Reactions Using P-Chirogenic Diaminophosphine Oxides: DIAPHOXs

4. Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions

5. The Synthesis of Chiral Phosphorus Ligands for use in Homogeneous Metal Catalysis

Cited by 31 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Crystal, Solution, and Computational Study of the Structure of Ortho‐Lithium N,N‐Diisopropyl‐P,P‐Diphenylphosphinothioic Amide;Chemistry – A European Journal;2024-01-31

2. A Powerful P−N Connection: Preparative Approaches, Reactivity, and Applications of P‐Stereogenic Aminophosphines;Chemistry – A European Journal;2024-01-15

3. Bulky P-stereogenic ligands. A success story in asymmetric catalysis;Coordination Chemistry Reviews;2023-08

4. Chiral Auxiliaries for the Synthesis of P-Chiral Phosphorus Derivatives;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023

5. Phosphorus (V) Stereochemistry and Industrial Applications;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2023