Distiboranes based on ortho-phenylene backbones as bidentate Lewis acids for fluoride anion chelation-Reference-Cited by-同舟云学术

Distiboranes based on ortho-phenylene backbones as bidentate Lewis acids for fluoride anion chelation

Published:2021 Issue:22 Volume:19 Page:4949-4957
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

You Di¹²³⁴,Zhou Benyu¹²³⁴,Hirai Masato¹²³⁴,Gabbaï François P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

Abstract

We report a new approach to fluorinated distiboranes by reaction of ortho-phenylene distibines with octafluorophenanthra-9,10-quinone. These new derivatives act as bidentate Lewis acids and readily chelate the fluoride anion.

Funder

Welch Foundation

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00536G

Reference82 articles.

1. Controlling the fluoridophilicity of sulfonium boranes via chelation, Coulombic and hydrophobic effects

2. Structural and Electrochemical Investigations of the High Fluoride Affinity of Sterically Hindered 1,8-Bis(boryl)naphthalenes

3. Hydride sponge: complexation of 1,8-naphthalenediylbis(dimethylborane) with hydride, fluoride, and hydroxide

4. Large-bite diboranes for the μ(1,2) complexation of hydrazine and cyanide

5. Exploiting the Strong Hydrogen Bond Donor Properties of a Borinic Acid Functionality for Fluoride Anion Recognition

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