Oxidation-dependent Lewis acidity in chalcogen adducts of Sb/P frustrated Lewis pairs-Reference-Cited by-同舟云学术

Oxidation-dependent Lewis acidity in chalcogen adducts of Sb/P frustrated Lewis pairs

Published:2024 Issue:28 Volume:53 Page:11762-11768
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Krieft Jonas¹,Neumann Beate¹,Stammler Hans-Georg¹,Mitzel Norbert W.¹^ORCID

Affiliation:

1. Chair of Inorganic and Structural Chemistry, Center for Molecular Materials CM2, Faculty of Chemistry, Bielefeld University, Universitätsstraße 25, Bielefeld 33615, Germany

Abstract

Sb(iii) to Sb(v) oxidation increases the Lewis acidity of the Sb atom of (F5C2)2SbCH2P(E)(tBu)2 (E = O, S, Se, Te). This “switch to strong” interaction between antimony and chalcogen atoms deforms the backbone while a four-membered cycle is formed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01591F

Reference69 articles.

1. Die Chloridionenaffinit�ten von Akzeptorchloriden in Acetonitril, 1. Mitt.: L�sungszustand und Bildungsgleichgewichte der Triphenylchlormethankomplexe

2. Chemistry in super acids. I. Hydrogen exchange and polycondensation of methane and alkanes in FSO3H-SbF5 ("magic acid") solution. Protonation of alkanes and the intermediacy of CH5+ and related hydrocarbon ions. The high chemical reactivity of "paraffins" in ionic solution reactions

3. Crossing Conventional Boundaries in Half a Century of Research

4. Methyl and ethyl hexafluoroantimonate and related compounds

5. The methyl fluoride-antimony pentafluoride and arsenic pentafluoride systems: the formation of methyl fluoride.antimony pentafluoride and methyl fluoride.arsenic pentafluoride and the methylation of thionyl fluoride and sulfuryl chloride fluoride

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