Axial fluoride binding by lanthanide DTMA complexes alters the local crystal field, resulting in dramatic spectroscopic changes-Reference-Cited by-同舟云学术

Axial fluoride binding by lanthanide DTMA complexes alters the local crystal field, resulting in dramatic spectroscopic changes

Published:2015 Issue:45 Volume:44 Page:19509-19517
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Blackburn Octavia A.¹²³⁴,Kenwright Alan M.⁵⁶⁷⁴,Beer Paul D.¹²³⁴,Faulkner Stephen¹²³⁴

Affiliation:

1. University of Oxford

2. Chemistry Research Laboratory

3. Oxford OX1 3TA

4. UK

5. Department of Chemistry

6. University of Durham

7. Durham DH1 3LE

Abstract

Dramatic changes are observed in both the NMR and luminescence spectra of LnDTMA complexes on addition of fluoride, consistent with a change in the nature of the magnetic anisotropy at the paramagnetic lanthanide centre.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02398J

Reference42 articles.

1. Gadolinium(III) Chelates as MRI Contrast Agents: Structure, Dynamics, and Applications

2. S. Faulkner and O. A.Blackburn, in The Chemistry of Molecular Imaging, ed. N. Long and W. T. Wong, Wiley, Chichester, 2015, ch. 8

3. Taking advantage of luminescent lanthanide ions

4. Lanthanide luminescence for functional materials and bio-sciences

5. Alternatives to Gadolinium-Based Metal Chelates for Magnetic Resonance Imaging

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