Extending the chemistry of carbones: P–N bond cleavage via an SN2′-like mechanism-Reference-Cited by-同舟云学术

Extending the chemistry of carbones: P–N bond cleavage via an SN2′-like mechanism

Published:2015 Issue:53 Volume:51 Page:10762-10764
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Gurnani Chitra¹²³⁴⁴,Đorđević Nemanja¹²³⁴⁴,Muthaiah Senthilkumar⁵⁶⁷,Dimić Dušan⁸⁹¹⁰¹¹,Ganguly Rakesh¹²³⁴⁴,Petković Milena⁸⁹¹⁰¹¹,Vidović Dragoslav¹²³⁴⁴

Affiliation:

1. School of Physical and Mathematical Sciences

2. Department of Chemistry and Biological Chemistry

3. Nanyang Technological University

4. Singapore

5. National Institute of Technology Kurukshetra

6. Kurukshetra-136119

7. India

8. Faculty of Physical Chemistry

9. University of Belgrade

10. 11000 Belgrade

11. Republic of Serbia

Abstract

The reaction of a couple of nucleophilic carbone molecules with RN(PCl₂)₂ (R = Me, Ph) revealed an unexpected and unique P–N bond cleavage via an S_N2′-like mechanism.

Funder

Agency for Science, Technology and Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC03194J

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