Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand-Reference-Cited by-同舟云学术

Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand

Published:2024-07-19 Issue:35 Volume:136 Page:
ISSN:0044-8249
Container-title:Angewandte Chemie
language:en
Short-container-title:Angewandte Chemie

Author:

Kooij Bastiaan¹^ORCID,Chen Damien W.¹,Fadaei‐Tirani Farzaneh¹,Severin Kay¹^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques Ecole Polytechnique Fédérale de Lausanne (EPFL) 1015 Lausanne Switzerland

Abstract

AbstractCarbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.202407945

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