Phosphine-free pincer-ruthenium catalyzed biofuel production: high rates, yields and turnovers of solventless alcohol alkylation-Reference-Cited by-同舟云学术

Phosphine-free pincer-ruthenium catalyzed biofuel production: high rates, yields and turnovers of solventless alcohol alkylation

Published:2020 Issue:24 Volume:10 Page:8347-8358
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Das Kanu¹²³⁴^ORCID,Yasmin Eileen¹²³⁴,Das Babulal¹²³⁴,Srivastava Hemant Kumar⁵⁶³⁴^ORCID,Kumar Akshai¹²³⁴⁷^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Guwahati

3. Guwahati

4. India

5. Department of Medicinal Chemistry

6. National Institute of Pharmaceutical Education and Research Guwahati

7. Centre for Nanotechnology

Abstract

High TONs and TOFs are observed for the β-alkylation of alcohols using phosphine-free pincer-ruthenium catalysts at a very low base loading. Kinetic studies and DFT calculations were complementary and provide a clear understanding on the mechanism.

Funder

Ministry of Human Resource Development

Science and Engineering Research Board

Indian Institute of Technology Guwahati

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY01679A

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