Efficient net transfer-dehydrogenation of glycerol: NNN pincer–Mn and manganese chloride as a catalyst unlocks the effortless production of lactic acid and isopropanol-Reference-Cited by-同舟云学术

Efficient net transfer-dehydrogenation of glycerol: NNN pincer–Mn and manganese chloride as a catalyst unlocks the effortless production of lactic acid and isopropanol

Published:2024 Issue:30 Volume:53 Page:12698-12709
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bisarya Akshara¹,Dhole Sunil²,Kumar Akshai¹³⁴^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati – 781039, Assam, India

2. ChemDist Group of Companies, Plot No 144 A, Sector 7, PCNTDA, Bhosari, Pune – 411026, Maharashtra, India

3. Center for Nanotechnology, Indian Institute of Technology Guwahati, Guwahati – 781039, Assam, India

4. Jyoti and Bhupat Mehta School of Health Sciences & Technology, Indian Institute of Technology Guwahati, Guwahati – 781039, Assam, India

Abstract

Glycerol to lactic acid conversion is accomplished with remarkable efficiency, achieving yields up to 92% with >99% selectivity by utilizing the base metal salt MnCl2·4H2O and its NNN pincer complexes as catalysts.

Funder

Ministry of Education, India

Indian Council of Medical Research

Ministry of Electronics and Information technology

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01731E

Reference66 articles.

1. The biorefinery concept: Using biomass instead of oil for producing energy and chemicals

2. Transfer Hydrogenation with Glycerol as H-Donor: Catalyst Activation, Deactivation and Homogeneity

3. Glycerol production and its applications as a raw material: A review

4. Glycerol Reforming for Hydrogen Production: A Review

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