The significance of the amorphous potential energy landscape for dictating glassy dynamics and driving solid-state crystallisation

Author:

Ruggiero Michael T.1234ORCID,Krynski Marcin5234ORCID,Kissi Eric Ofosu6789ORCID,Sibik Juraj1234ORCID,Markl Daniel1234ORCID,Tan Nicholas Y.1234,Arslanov Denis1011121314,van der Zande Wim1011121314,Redlich Britta1011121314ORCID,Korter Timothy M.5151617ORCID,Grohganz Holger6789ORCID,Löbmann Korbinian6789ORCID,Rades Thomas6789ORCID,Elliott Stephen R.5234,Zeitler J. Axel1234ORCID

Affiliation:

1. Department of Chemical Engineering and Biotechnology

2. University of Cambridge

3. Cambridge

4. UK

5. Department of Chemistry

6. Department of Pharmacy

7. University of Copenhagen

8. 2100 Copenhagen

9. Denmark

10. Radboud University

11. Institute for Molecules and Materials

12. FELIX Laboratory

13. 6252 ED Nijmegen

14. The Netherlands

15. Syracuse University

16. Syracuse

17. USA

Abstract

We show clear evidence for a theory proposing that the shape and structure of the PES is the fundamental factor underlying the dynamics at temperatures below the glass transition.

Funder

Royal Society of Chemistry

Engineering and Physical Sciences Research Council

FP7 Coordination of Non-Community Research Programmes

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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