Tetranuclear oxido-bridged thorium(iv) clusters obtained using tridentate Schiff bases

Author:

Tsantis Sokratis T.1234ORCID,Lagou-Rekka Aimilia1234,Konidaris Konstantis F.12345,Raptopoulou Catherine P.6784,Bekiari Vlasoula5294,Psycharis Vassilis6784,Perlepes Spyros P.123410ORCID

Affiliation:

1. Department of Chemistry

2. University of Patras

3. Patras

4. Greece

5. School of Agriculture Sciences

6. Institute of Nanoscience and Nanotechnology

7. NCSR “Demokritos”

8. 15310 Aghia Paraskevi Attikis

9. 30200 Messolonghi

10. Foundation for Research and Technology-Hellas (FORTH)

Abstract

The reactions of tetravalent thorium, an element named after the Scandinavian God of thunder and war, with tridentate Schiff bases give tetranuclear complexes with the extremely rare {ThIV4(μ4-O)} unit and interesting properties.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference90 articles.

1. Thorium(iv) alkyl and allyl complexes of a rigid NON-donor pincer ligand with flanking 1-adamantyl substituents

2. F. A. Cotton , G.Wilkinson , C. A.Murillo and M.Bochmann , Advanced Inorganic Chemistry , Wiley , New York , 6th edn, 1999 , pp. 1130–1164

3. C. E. Housecroft and A. G.Sharpe , Inorganic Chemistry , Pearson Harlow , UK , 5th edn, 2018 , pp. 1033–1064

4. M. S. Wickleder , B.Fourest and P. K.Dorhout , in The Chemistry of the Actinide and Transactinide Elements , ed. L. R. Morss , N. M. Edelstein and J. Fuger , Springer , Dordrecht, The Netherlands , 4th edn, 2010 , vol. 1 , ch. 3, pp. 52–133

5. Thorium lends a fiery hand

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