In search of tris(trimethylsilylcyclopentadienyl) thorium
Author:
Affiliation:
1. Department of Chemistry
2. University of California
3. Irvine
4. USA
Abstract
Solution synthesis, characterization, and reactivity of a new Th(iii) complex Cp′3Th (Cp′ = C5H4SiMe3).
Funder
Basic Energy Sciences
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03674A
Reference45 articles.
1. Electron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (II-III) oxidation potential for each member of the lanthanide and actinide series
2. Lanthanide thermodynamic predictions. 7. Thermodynamics of 2+, 3+, and 4+ aquo ions and standard electrode potentials at 298.15 K
3. About the existence of Th(III) in aqueous solution
4. The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes
5. The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure
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