Selective hydrogenation of acetylene on the PdLa@N-doped biochar catalyst surface: the evolution of active sites, catalytic performance, and mechanism
Author:
Affiliation:
1. Faculty of Environmental Science and Engineering
2. Kunming University of Science and Technology
3. Kunmin
4. China
5. Faculty of Chemical Engineering
6. Kunming, Yunnan 650500
7. Faculty of Civil Engineering and Mechanics
8. Kunming
Abstract
The high specific surface area of the support and the active site separation effect caused by the doping of La jointly promoted the high conversion rate of acetylene and the high selectivity of ethylene.
Funder
National Natural Science Foundation of China
National Key Research and Development Program of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ04401F
Reference54 articles.
1. Origin of the Increase of Activity and Selectivity of Nickel Doped by Au, Ag, and Cu for Acetylene Hydrogenation
2. Model-Based Optimization of an Acetylene Hydrogenation Reactor To Improve Overall Ethylene Plant Economics
3. Selective Hydrogenation of Acetylene to Ethylene Over Nanosized Gold and Palladium Supported Catalysts
4. Copper-substituted ethanes as a model for copper-acetylene interactions on the metal surface Quantum mechanical study of the structure and bonding of copper-acetylene and copper-ethylene compounds Cun(C2H2) (n = 1, 2, 4), Cu(C2H2) +, Cun(C2H4 (n = 1, 2) and Cu(C2H4)+1,2
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