Rigid NON-donor pincer ligand complexes of lutetium and lanthanum: synthesis and hydroamination catalysis
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology
2. McMaster University
3. Hamilton
4. Canada
5. McMaster Analytical X-Ray (MAX) Diffraction Facility
Abstract
A rigid NON-donor pincer ligand was employed for the synthesis of neutral lutetium and anionic lanthanum alkyl complexes; the former is highly active for both intra- and inter-molecular hydroamination.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA04432A
Reference41 articles.
1. Early Transition Metal (Group 3–5, Lanthanides and Actinides) and Main Group Metal (Group 1, 2, and 13) Catalyzed Hydroamination
2. Organolanthanide-Catalyzed Hydroamination
3. Hydroamination: Direct Addition of Amines to Alkenes and Alkynes
4. Asymmetric Hydroamination
5. Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds
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