Group 3 dialkyl complexes of a rigid monoanionic NNN-donor pincer ligand: synthesis, structures, unexpected reactivity with CPh<sub>3</sub><sup>+</sup>, and hydroamination catalysis-Reference-Cited by-同舟云学术

Group 3 dialkyl complexes of a rigid monoanionic NNN-donor pincer ligand: synthesis, structures, unexpected reactivity with CPh₃⁺, and hydroamination catalysis

Published:2023 Issue:17 Volume:52 Page:5642-5651
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vasanthakumar Aathith¹,Gray Novan A. G.¹^ORCID,Franko Christopher J.¹,Murphy Maia C.¹,Emslie David J. H.¹^ORCID

Affiliation:

1. Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario L8S 4M1, Canada

Abstract

A rigid new monoanionic pincer ligand was used to prepare yttrium and scandium dialkyl complexes, and reactivity with CPh3+ is described.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00530E

Reference92 articles.

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4. Extremely Stable Thorium(IV) Dialkyl Complexes Supported by Rigid Tridentate 4,5-Bis(anilido)xanthene and 2,6-Bis(anilidomethyl)pyridine Ligands

5. Divergent reactivity of [(κ3-L)ThCl2(dme)] with Grignard reagents: Alkylation, ancillary ligand transfer to magnesium, and halide exchange caught in the act

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