Low-spin and spin-crossover iron(ii) complexes with pyridyl-benzimidazole ligands: synthesis, and structural, magnetic and solution study

Author:

Brachňaková Barbora12345,Adamko Kožíšková Júlia62345,Kožíšek Jozef62345,Melníková Eva72345,Gál Miroslav72345,Herchel Radovan1891011ORCID,Dubaj Tibor62345,Šalitroš Ivan12345ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Faculty of Chemical and Food Technology

3. Slovak University of Technology in Bratislava

4. Bratislava SK-81237

5. Slovakia

6. Department of Physical Chemistry

7. Department of Inorganic Technology

8. Regional Centre of Advanced Technologies and Materials

9. Faculty of Science

10. Palacký University

11. 771 46 Olomouc

Abstract

Novel derivatives of tri- and didentate pyridyl-benzimidazole ligands were employed for the synthesis of ferrous complexes showing either low-spin or room temperature spin crossover.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Univerzita Palackého v Olomouci

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference61 articles.

1. Spin Crossover in Transition Metal Compounds I – III , in Topics in Current Chemistry , ed. P. Gutlich and H. A. Goodwin , Springer , Berlin/Heidelberg , 2004 , pp. 233–235

2. Spin-crossover in iron(ii)-Schiff base complexes

3. Spin-Crossover Materials: Properties and Applications , ed. M. A. Halcrow , John Wiley & Sons Ltd , Chichester , 2013

4. Molecular spin crossover phenomenon: recent achievements and prospects

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