Pyridyl-benzimidazole derivatives decorated with phenylazo substituents and their low-spin iron(<scp>ii</scp>) complexes: a study of the synthesis, structure and photoisomerization-Reference-Cited by-同舟云学术

Pyridyl-benzimidazole derivatives decorated with phenylazo substituents and their low-spin iron(ii) complexes: a study of the synthesis, structure and photoisomerization

Published:2023 Issue:3 Volume:47 Page:1488-1497
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Orvoš Jakub¹,Fischer Róbert¹^ORCID,Brachňaková Barbora²³,Pavlik Ján²^ORCID,Moncoľ Ján²^ORCID,Šagátová Alexandra²,Fronc Marek⁴,Kožíšek Jozef⁴^ORCID,Routaboul Lucie³^ORCID,Bousseksou Azzedine³,Šalitroš Ivan²⁵⁶^ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Bratislava SK-81237, Slovakia

2. Department of Inorganic Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Bratislava SK-81237, Slovakia

3. LCC, CNRS & Université de Toulouse, 205 route de Narbonne, 31077 Toulouse, France

4. Department of Physical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Bratislava SK-81237, Slovakia

5. Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic

6. Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic

Abstract

Series of phenylazo substituted pyridyl-benzimidazole ligands and their ferrous complexes have been prepared. Photoirradiation experiments allowed to investigate E–Z isomerisation of ligands, which was further rationalized by computational study.

Funder

Grantová Agentura České Republiky

European Regional Development Fund

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Kultúrna a Edukacná Grantová Agentúra MŠVVaŠ SR

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ04774H