In situ high-energy synchrotron X-ray diffraction studies and first principles modeling of α-MnO2 electrodes in Li–O2 and Li-ion coin cells
Author:
Affiliation:
1. Chemical Sciences and Engineering Division
2. Argonne National Laboratory
3. Argonne
4. USA
5. X-ray Science Division
6. Advanced Photon Source
7. Center for Nanoscale Materials
Abstract
In situ synchrotron diffraction and first principles modeling shows structural changes in α-MnO2 during cycling in Li–O2 battery cells, as lithium and oxygen are incorporated into and removed from tunnels in the structure.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/TA/C4TA06633B
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