Metal-free oxidative esterification of acetophenones with alcohols: a facile one-pot approach to α-ketoesters-Reference-Cited by-同舟云学术

Metal-free oxidative esterification of acetophenones with alcohols: a facile one-pot approach to α-ketoesters

Published:2016 Issue:100 Volume:6 Page:98422-98426
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Guo Shiyu¹²³⁴,Dai Zhongxue¹²³⁴,Yang Zhao⁵⁶³⁴,Zhu Ning¹²³⁴,Wan Li¹²³⁴,Li Xin¹²³⁴,Liu Chengkou¹²³⁴,Fang Zheng¹²³⁴,Guo Kai¹²³⁴⁷^ORCID

Affiliation:

1. College of Biotechnology and Pharmaceutical Engineering

2. Nanjing Tech University

3. Nanjing

4. China

5. College of Engineering

6. China Pharmaceutical University

7. State Key Laboratory of Materials-Oriented Chemical Engineering

Abstract

A novel oxidative esterification method for the synthesis of α-ketoesters has been developed, which is a facile one-pot approach to α-ketoesters from acetophenones with alcohols, especially under metal-free conditions with broad substrate scope.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA19485K

Reference46 articles.

1. New 4-Methoxybenzoyl Derivatives from the Ascidian Polycarpa aurata

2. Enantioselective Synthesis of Tertiary Alcohols through a Zirconium-Catalyzed Friedel–Crafts Alkylation of Pyrroles with α-Ketoesters

3. Novel anti-Prelog stereospecific carbonyl reductases from Candida parapsilosis for asymmetric reduction of prochiral ketones

4. Highly Enantioselective Intermolecular Stetter Reactions of β-Aryl Acceptors: α-Ketoester Moiety as Handle for Activation and Synthetic Manipulations

5. 1,3-Phenylene bis(ketoacid) derivatives as inhibitors of Escherichia coli dihydrodipicolinate synthase

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