Insights into mechanism and selectivity in ruthenium(ii)-catalysed ortho-arylation reactions directed by Lewis basic groups
Author:
Affiliation:
1. WestCHEM Department of Pure and Applied Chemistry
2. University of Strathclyde
3. Glasgow
4. UK
5. Institut de Química Computacional i Catàlisi and Departament de Química
6. Campus Montilivi
7. Universitat de Girona
8. 17003 Girona
9. Spain
Abstract
We report a detailed study of the mechanism and selectivity of ruthenium-catalysed C–H arylation reactions directed by Lewis basic heterocycles.
Funder
University of Strathclyde
European Commission
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00592C
Reference60 articles.
1. Understanding and exploiting C–H bond activation
2. Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization
3. Site-selective and stereoselective functionalization of unactivated C–H bonds
4. Unraveling innate substrate control in site-selective palladium-catalyzed C–H heterocycle functionalization
5. Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh
Cited by 26 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. DLPNO-CCSD(T) and DFT study of the acetate-assisted C–H activation of benzaldimine at [RuCl2(p-cymene)]2: the relevance of ligand exchange processes at ruthenium(ii) complexes in polar protic media;Dalton Transactions;2024
2. A Predictive Model for the Pd‐Catalyzed Site‐Selective Oxidation of Diols;Chemistry – A European Journal;2023-07-08
3. Pd-Catalyzed Asymmetric Oxidative C–H/C–H Cross-Coupling Reaction between Ferrocenes and Azoles;The Journal of Organic Chemistry;2023-04-21
4. Precise control of the site selectivity in ruthenium-catalyzed C–H bond amidations using cyclic amides as powerful directing groups;Organic Chemistry Frontiers;2023
5. Switchable cyclopalladation of substrates containing two directing groups: on the way to non-symmetrical [2.2]-dipalladaparacyclophanes;Dalton Transactions;2023
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3