Switchable cyclopalladation of substrates containing two directing groups: on the way to non-symmetrical [2.2]-dipalladaparacyclophanes

Author:

Korábková Tereza1,Bartáček Jan1,Marek Lukáš1ORCID,Hanusek Jiří1ORCID,Růžička Aleš2ORCID,Váňa Jiří1ORCID

Affiliation:

1. Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 53210 Pardubice, The Czech Republic

2. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 53210 Pardubice, The Czech Republic

Abstract

The regioselectivity of C–H activation reactions of substrates with multiple directing groups can be easily switched using additional acids.

Funder

University of Pardubice

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

1. Palladacycles , ed. J. Dupont and M. Pfeffer , 2008 WILEY-VCH Verlag GmbH & Co. KGaA , Weinheim , ISBN: 978-3-527-31781-3

2. A.Kapdi and D.Maiti , Strategies for Palladium-Catalyzed Non-directed and Directed C-H Bond Functionalization , Elsevier 2017 , Paperback ISBN: 9780128052549

3. C–H activation

4. Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

5. A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

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