Steep sulfur gradient in CZTSSe solar cells by H2S-assisted rapid surface sulfurization

Author:

Taskesen Teoman12345ORCID,Pareek Devendra12345ORCID,Hauschild Dirk67859ORCID,Haertel Alan67859,Weinhardt Lothar67859ORCID,Yang Wanli10111213ORCID,Pfeiffelmann Timo12345,Nowak David12345,Heske Clemens67859ORCID,Gütay Levent12345ORCID

Affiliation:

1. Ultrafast Nanoscale Dynamics (UND) Workgroup

2. Institute of Physics

3. Carl von Ossietzky University of Oldenburg

4. D-26129 Oldenburg

5. Germany

6. Institute for Photon Science and Synchrotron Radiation (IPS)

7. Karlsruhe Institute of Technology (KIT)

8. D-76344 Eggenstein-Leopoldshafen

9. Institute for Chemical Technology and Polymer Chemistry (ITCP)

10. Advanced Light Source (ALS)

11. Lawrence Berkeley National Laboratory

12. Berkeley

13. USA

Abstract

This article demonstrates a flash-type kinetic sulfurization method to introduce band-gap grading in CZTSe based photovoltaic devices. The developed approach allows to achieve a steep grading profile on kesterite thin-film surface.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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