Changing the path of least resistance, or access to endo-dig products via a sequence of three exo-trig transition states: electronic effects in homoallyic ring expansion cascades of alkenyl isonitriles
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Florida State University
3. Tallahassee
4. USA
Abstract
Substituent effects reshape the potential energy surfaces for radical homoallylic expansion/fragmentation cascades that transform alkenyl isonitriles into N-heteroaromatics
Funder
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00527J
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4. A new tributyltin hydride-based rearrangement of bromomethyl .beta.-keto esters. A synthetically useful ring expansion to .gamma.-keto esters
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