Highly thermally stable and robust enantiopure zirconium NNN-scorpionates for the controlled ring-opening polymerization of rac-lactide-Reference-Cited by-同舟云学术

Highly thermally stable and robust enantiopure zirconium NNN-scorpionates for the controlled ring-opening polymerization of rac-lactide

Published:2017 Issue:20 Volume:46 Page:6654-6662
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Otero Antonio¹²³⁴⁵^ORCID,Fernández-Baeza Juan¹²³⁴⁵,Garcés Andrés⁶⁷⁸⁹¹⁰,Sánchez-Barba Luis F.⁶⁷⁸⁹¹⁰,Lara-Sánchez Agustín¹²³⁴⁵^ORCID,Martínez-Ferrer Jaime¹²³⁴⁵,Carrión María P.¹²³⁴⁵,Rodríguez Ana M.¹²³⁴⁵

Affiliation:

1. Universidad de Castilla-La Mancha

2. Departamento de Química Inorgánica

3. Orgánica y Bioquímica

4. Centro de Innovación en Química Avanzada (ORFEO-CINQA) Campus Universitario

5. 13071-Ciudad Real

6. Universidad Rey Juan Carlos

7. Departamento de Biología y Geología

8. Física y Química Inorgánica

9. Móstoles-28933-Madrid

10. Spain

Abstract

An enantiopure NNN-scorpionate zirconium alkoxide as the highest active group 4-based initiator in ROP of unpurified rac-LA under industrially preferred conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01050H

Reference55 articles.

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5. Metal catalysts for ε-caprolactone polymerisation

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