Sterically encumbered metalla-diphosphines: unlocking alkyne rotation by PtII coordination-Reference-Cited by-同舟云学术

Sterically encumbered metalla-diphosphines: unlocking alkyne rotation by PtII coordination

Published:2017 Issue:34 Volume:46 Page:11140-11144
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Helmdach Kai¹²³⁴,Dörk Stephan¹²³⁴,Villinger Alexander¹²³⁴,Seidel Wolfram W.¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie

2. Universität Rostock

3. 18059 Rostock

4. Germany

Abstract

Chelate coordination of a redoxactive metalla-diphosphine at PtCl₂ changes the electronic structure at the alkyne complex moiety significantly, which is reflected in the onset of rotational isomerism.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01803G

Reference38 articles.

1. Phosphorus Compounds. Advanced Tools in Catalysis and Material Sciences, ed. M. Peruzzini and L. Gonsalvi, Springer, Dordrecht, Netherlands, 2011

2. Phosphorus(III)Ligands in Homogeneous Catalysis. Design and Synthesis, ed. P. C. J. Kamer and P. W. N. M. van Leeuwen, John Wiley & Sons, Chichester, UK, 2012

3. Redox-Active Ligands in Catalysis

4. Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

5. Redox-active ligands in catalysis

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