The long-sought seventeen-electron radical [(C6Me6)Cr(CO)3]+: isolation, crystal structure and substitution reaction-Reference-Cited by-同舟云学术

The long-sought seventeen-electron radical [(C6Me6)Cr(CO)3]+: isolation, crystal structure and substitution reaction

Published:2015 Issue:40 Volume:51 Page:8410-8413
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Wenqing¹²³⁴⁵,Wang Xingyong¹²³⁴⁵,Zhang Zaichao²⁶⁷⁸,Yuan Ningning¹²³⁴⁵,Wang Xinping¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. School of Chemistry and Chemical Engineering

3. Collaborative Innovation Center of Advanced Microstructures

4. Nanjing University

5. Nanjing 210093

6. Huaiyin Normal University

7. Huai'an 223300

8. China

Abstract

A highly air-sensitive seventeen-electron half-sandwich radical, [(C₆Me₆)Cr(CO)₃]⁺, which has been long sought over 40 years, was isolated and structurally characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC01941A

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