Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP]<sub>2</sub> (X = Cl, Br) and their facile oxidation to radical cations-Reference-Cited by-同舟云学术

Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP]₂ (X = Cl, Br) and their facile oxidation to radical cations

Published:2022 Issue:43 Volume:13 Page:12643-12650
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sharma Mahendra K.¹^ORCID,Chabbra Sonia²^ORCID,Wölper Christoph¹,Weinert Hanns M.¹^ORCID,Reijerse Edward J.²^ORCID,Schnegg Alexander²^ORCID,Schulz Stephan¹³^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, University of Duisburg-Essen, Universitätsstraße 5-7, D-45141, Essen, Germany

2. EPR Research Group, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, Mülheim an der Ruhr, D-45470, Germany

3. Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Carl-Benz-Straße 199, 47057 Duisburg, Germany

Abstract

Carbene-coordination allowed for one-electron oxidation of diphosphenes [LGa(X)P]2 to P-centered radicals cations 4a (X = Cl) and 4b (X = Br), in which the unpaired spin mainly reside at the carbene uncoordinated P-atoms.

Funder

Deutsche Forschungsgemeinschaft

Universität Duisburg-Essen

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04207J

Reference104 articles.

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2. Persistent and Stable Radicals of the Heavier Main Group Elements and Related Species