Revealing the contributions of homogeneous and heterogeneous catalysis to isomerization of d-glucose into d-fructose in the presence of basic salts with low solubility

Author:

Toussaint Valérie12ORCID,Delidovich Irina12ORCID

Affiliation:

1. Institute of Chemical, Environmental and Bioscience Engineering, TU Wien, Getreidemarkt 9, 1060 Vienna, Austria

2. Chair of Heterogeneous Catalysis and Chemical Technology, Institute for Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

Abstract

Hydroxide anions are identified as catalytically active species for the isomerization of d-glucose to d-fructose over low soluble basic salts. The highest selectivity for d-fructose was obtained for catalysis by MgCO3.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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