Intrinsic hydrogen evolution capability and a theoretically supported reaction mechanism of a paddlewheel-type dirhodium complex-Reference-Cited by-同舟云学术

Intrinsic hydrogen evolution capability and a theoretically supported reaction mechanism of a paddlewheel-type dirhodium complex

Published:2019 Issue:21 Volume:48 Page:7302-7312
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kataoka Yusuke¹²³⁴⁵^ORCID,Yano Natsumi¹²³⁴⁵^ORCID,Handa Makoto¹²³⁴⁵^ORCID,Kawamoto Tatsuya¹⁶⁷⁸⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Natural Science and Technology

3. Shimane University

4. Shimane

5. Japan

6. Faculty of Science

7. Kanagawa University

8. Kanagawa

Abstract

The intrinsic capability of the paddlewheel-type dirhodium tetraacetate complex, [Rh₂(O₂CCH₃)₄(H₂O)₂] ([1(H2O)2]), as a hydrogen evolution catalyst (HEC) for photochemical hydrogen evolution from aqueous solution was illustrated.

Funder

Japan Society for the Promotion of Science

Shorai Foundation for Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT05035J

Reference61 articles.

1. Electrochemical Photolysis of Water at a Semiconductor Electrode

2. Artificial photosynthesis: water cleavage into hydrogen and oxygen by visible light

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