Spontaneous N2-diboranylation of [W(N2)2(dppe)2] with B2Br4(SMe2)2

Author:

Haufe Lisa C.12,Arrowsmith Merle12ORCID,Dietz Maximilian12,Gärtner Annalena12,Bertermann Rüdiger12,Braunschweig Holger12ORCID

Affiliation:

1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074, Würzburg, Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

The spontaneous 1,3-bromoboration of a tungsten dinitrogen complex with B2Br2(SMe2)2 yields diazenidodiborane complexes.

Funder

Studienstiftung des Deutschen Volkes

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference57 articles.

1. G. J.Leigh , in Nitrogen Fixation: Origins, Applications, and Research Progress , ed. B. E. Smith , R. L. Richards and W. E. Newton , Springer , Dordrecht , 2004 , vol. 1 , p. 33

2. Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

3. Nitrogen Fixation via Splitting into Nitrido Complexes

4. Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions

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