An orbitally adapted push–pull template for N<sub>2</sub> activation and reduction to diazene-diide-Reference-Cited by-同舟云学术

An orbitally adapted push–pull template for N₂ activation and reduction to diazene-diide

Published:2023 Issue:48 Volume:14 Page:14262-14270
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Specklin David¹,Boegli Marie-Christine¹,Coffinet Anaïs¹,Escomel Léon¹,Vendier Laure¹,Grellier Mary¹,Simonneau Antoine¹^ORCID

Affiliation:

1. LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, F-31077 Toulouse Cedex 4, France

Abstract

The first two-fold Lewis acid adduct of a terminal N2 ligand was prepared by employing a bis(borane). The influence of double coordination is benchmarked against the adduct of a related, non-chelating Lewis acid.

Funder

H2020 European Research Council

Ministère de l'Education Nationale, de l'Enseignement Supérieur et de la Recherche

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04390H

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