Fundamental electronic changes upon intersystem crossing in large aromatic photosensitizers: free base 5,10,15,20-tetrakis(4-carboxylatophenyl)porphyrin-Reference-Cited by-同舟云学术

Fundamental electronic changes upon intersystem crossing in large aromatic photosensitizers: free base 5,10,15,20-tetrakis(4-carboxylatophenyl)porphyrin

Published:2022 Issue:12 Volume:24 Page:7505-7511
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Büchner Robby¹²^ORCID,Vaz da Cruz Vinícius²^ORCID,Grover Nitika³^ORCID,Charisiadis Asterios³,Fondell Mattis²^ORCID,Haverkamp Robert¹²,Senge Mathias O.⁴^ORCID,Föhlisch Alexander¹²^ORCID

Affiliation:

1. Institute of Physics and Astronomy, University of Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Potsdam, Germany

2. Institute for Methods and Instrumentation for Synchrotron Radiation Research, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Str. 15, 12489, Berlin, Germany

3. School of Chemistry, Chair of Organic Chemistry, Trinity College Dublin, The University of Dublin, Trinity Biomedical Sciences Institute, 152-160 Pearse Street, Dublin 2, Ireland

4. Institute for Advanced Study, Technical University of Munich, Lichtenbergstrasse 2a, 85748 Munchen Garching, Germany

Abstract

The crucial transient states of free-base porphyrins are characterized by time-resolved X-ray absorption spectroscopy unraveling their unusual relaxation pathway.

Funder

Higher Education Authority

H2020 European Research Council

Technische Universität München

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP05420A

Reference67 articles.

1. Bridging the Green Gap: Metal–Organic Framework Heteromultilayers Assembled from Porphyrinic Linkers Identified by Using Computational Screening