Americium(iii) and europium(iii) complex formation with lactate at elevated temperatures studied by spectroscopy and quantum chemical calculations-Reference-Cited by-同舟云学术

Americium(iii) and europium(iii) complex formation with lactate at elevated temperatures studied by spectroscopy and quantum chemical calculations

Published:2014 Issue:29 Volume:43 Page:11221-11232
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Barkleit Astrid¹²³⁴⁵,Kretzschmar Jerome¹²³,Tsushima Satoru¹²³,Acker Margret⁶⁷⁸

Affiliation:

1. Institute of Resource Ecology

2. Helmholtz-Zentrum Dresden – Rossendorf

3. 01314 Dresden, Germany

4. Radiochemistry

5. Department of Chemistry and Food Chemistry

6. Central Radionuclide Laboratory

7. Technische Universität Dresden

8. 01062 Dresden, Germany

Abstract

Spectroscopic techniques (NMR and ATR FT-IR) in combination with calculations (DFT) show that the hydroxyl group of the lactate is deprotonated under complex formation with Eu(iii).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00440J

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5. Structural, Luminescence, and NMR Studies of the Reversible Binding of Acetate, Lactate, Citrate, and Selected Amino Acids to Chiral Diaqua Ytterbium, Gadolinium, and Europium Complexes

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