Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb

Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)

Published:2023-10-01 Issue:10 Volume:68 Page:1422-1432
ISSN:0044-457X
Container-title:Журнал неорганической химии
language:
Short-container-title:Žurnal neorganičeskoj himii

Author:

Golikova M. V.¹,Yapryntsev A. D.¹,Jia Ch.²,Fatyushina E. V.¹,Baranchikov A. E.¹,Ivanov V. K.¹²

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

2. Moscow State University

Abstract

A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C3H5O3)3(H2O)2] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.

Publisher

The Russian Academy of Sciences

Reference46 articles.

1. Janicki R., Mondry A., Starynowicz P. // Coord. Chem. Rev. 2017. V. 340. P. 98. https://doi.org/10.1016/j.ccr.2016.12.001

2. Shmelev M.A., Gogoleva N.V., Ivanov V.K. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 9. P. 539. https://doi.org/10.1134/S1070328422090056

3. Shmelev M.A., Voronina Y.K., Gogoleva N.V. et al. // Russ. J. Coord. Chem. 2022. V. 48. № 4. P. 224. https://doi.org/10.1134/S1070328422040042

4. Boskovic C. // Acc. Chem. Res. 2017. V. 50. № 9. P. 2205. https://doi.org/10.1021/acs.accounts.7b00197

5. Stock N., Biswas S. // Chem. Rev. 2012. V. 112. № 2. P. 933. https://doi.org/10.1021/cr200304e