Using the Ni-[(benzylprolyl)amino]benzophenone complex in the Glaser reaction for the synthesis of bis α-amino acids

Author:

Mkrtchyan Anna F.12345ORCID,Hayriyan Liana A.564,Karapetyan Ani J.12345,Tovmasyan Anna S.12345,Tsaturyan Avetis H.12345,Khrustalev Victor N.7891011,Maleev Viktor I.1211139ORCID,Saghyan Ashot S.12345ORCID

Affiliation:

1. Institute of Pharmacy

2. Yerevan State University

3. 0025 Yerevan

4. Armenia

5. Scientific and Production Center “Armbiotechnology” of NAS RA

6. 0056 Yerevan

7. Peoples’ Friendship University of Russia (RUDN University)

8. 117198 Moscow

9. Russian Federation

10. N.D. Zelinsky Institute of Organic Chemistry

11. Russian Academy of Sciences

12. A.N. Nesmeyanov Institute of Organoelement Compounds

13. 119991 Moscow

Abstract

Enantiomerically enriched (S)-α-amino acids were obtained. As the initial complex, the Schiff base Ni(ii) complexes were used. The target Ni(ii) complexes were disassembled and the amino acids were isolated with excellent enantioselectivities.

Funder

International Science and Technology Center

Armenian National Science and Education Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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