An asymmetric metal-templated route to amino acids with an isoquinolone core <i>via</i> a Rh(<scp>iii</scp>)-catalyzed coupling of aryl hydroxamates with chiral propargylglycine Ni(<scp>ii</scp>) complexes-Reference-Cited by-同舟云学术

An asymmetric metal-templated route to amino acids with an isoquinolone core via a Rh(iii)-catalyzed coupling of aryl hydroxamates with chiral propargylglycine Ni(ii) complexes

Published:2022 Issue:47 Volume:20 Page:9385-9391
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Arsenov Mikhail A.¹,Stoletova Nadezhda V.¹,Savel'yeva Tat'yana F.¹,Smol'yakov Alexander F.¹²,Maleev Victor I.¹^ORCID,Loginov Dmitry A.¹²^ORCID,Larionov Vladimir A.¹³^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS), Vavilov Str. 28, 119991 Moscow, Russian Federation

2. Plekhanov Russian University of Economics, Stremyanny Per. 36, 117997 Moscow, Russian Federation

3. Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya Str. 6, 117198 Moscow, Russian Federation

Abstract

The first asymmetric route to artificial amino acids with an isoquinolone skeleton was elaborated via a straightforward Rh(iii)-catalyzed C–H activation/annulation reaction.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01970A

Reference84 articles.

1. Isoquinoline neurotoxins in the brain and Parkinson's disease

2. Isoquinoline Alkaloids and their Binding with DNA: Calorimetry and Thermal Analysis Applications